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This bulletin describes preventive
maintenance and recommended charging procedures to maximize
battery life. The leading cause of premature battery failure
is improper charging and poor battery maintenance.. To avoid
battery sulfation, a lead acid battery must be equalized or
given a controlled overcharge on a regular preventive basis.
Equalization is very important and must be preformed
correctly but only as required.
Preventive Maintenance
When a battery is first received the
cell acid levels should be checked and the battery should be
put on charge. After removing from charge the specific
gravity readings of each cell should be recorded and kept
for the life of the battery.. If the electrolyte levels are
low before the battery is put into service do not add water
but contact your dealer or Surrette Battery Company Limited.
Only add water as it is consumed.
Preventive maintenance involves,
at a minimum, checking the cell electrolyte level for
correct acid volume once a month and equalizing once every
six months. The cells should be watered back to the
original acid level which is 1/4 - 1/2" below the bottom
of the vent well (tube inside the battery cell with slots
on each side). Distilled water is preferred but local
water (not chlorinated) maybe acceptable if it is not
"hard" or does not contain high iron levels. Use of
non-distilled water can cause mineral build-up in the
battery cell.

The minimum recommended preventive
maintenance program is summarized as follows:
-
Water each cell to original level
as required
-
Equalize as required or once every
six months
-
Record the specific gravity
readings of each cell every three months.
Occasionally cleaning the battery
terminals and case / cover is a good practice and
recommended. A weak solution of household baking soda and
water can be used to neutralize any spilled acid (100 g per
liter or 4 Oz per pint). Make sure the vent caps are
securely tightened and NO soda solution gets into the
battery cells.
Good record keeping is stressed as
review of these records can help to determine the "health"
of the battery and can prove invaluable if system problems
develop.
When the bank is first put into
service a pilot cell should be monitored to assure the
batteries are being properly charged. Measure and record the
specific gravity of the pilot cell when the battery is
thought to be fully charged (after the bulk charge) and
compare this with the previous reading.
State of
Charge and Charging
The truest measure of a battery's
state of charge is the SPECIFIC GRAVITY of the battery acid.
The following shows the approximate state of charge at
various specific gravities at 77ºF / 25ºC.
|
System Setup |
Percentage of Charged |
Specific Gravity |
|
12V |
24V |
36V |
48V |
|
12.66 |
25.32 |
37.98 |
50.64 |
100% |
1.265-1.275 |
|
12.45 |
25.90 |
37.35 |
49.80 |
75% |
1.225-1.235 |
|
12.24 |
24.48 |
36.72 |
48.96 |
50% |
1.190-1.200 |
|
12.06 |
24.12 |
36.18 |
48.24 |
25% |
1.155-1.165 |
|
11.89 |
23.78 |
35.67 |
47.56 |
0% |
1.120-1.130 |
Hydrometers can be difficult to use
and at best accurate to +/-0.005 points. Please see Bulletin
606 for correct hydrometer use. Voltage can be used to
estimate state of charge but caution must be taken when
interpreting voltage readings. See, Bulletin 609, Voltage,
Specific Gravity and State of Charge.
We recommend a three step charging
procedure. Recommended voltage settings are as follows:
|
|
Volts per cell
|
12V
|
24V
|
36V |
48V
|
|
Equalization |
2.58 -2.67 (max)
|
15.5-16.0
|
31.0-32.0
|
46.5-48.0 |
61.9-64.1
|
|
Absorption/Bulk |
2.37-2.45 (max)
|
14.2-14.7
|
28.4-29.4
|
42.6-44.1 |
56.9-58.8
|
|
Float
|
2.20-2.23 (max)
|
13.2-13.4
|
26.4-26.8
|
39.6-40.2 |
52.8-53.5
|
To calculate the correct settings
for another battery bank voltage divide the total nominal
voltage by two and use this number as a multiplier. For
example a 18V system, 18/ 2 = 9, equalization preferred = 9
x 2.58 = 23.2 V
Caution:
The ideal float voltage is the lowest voltage setting that
will maintain the battery at full charge. The higher the
voltage the more water the cell will consume. The minimum
equalization voltage is highly recommended unless it is
suspected a sulfation problem exists and a corrective
equalization is required.
Absorption times are dependent on
the battery series (4000 or 5000). The recommended times are
general guidelines and the optimum time is dependent on
absorption (bulk) voltage settings, charging current and
should be adjusted such the batteries are brought back to
full charge and use a small amount of water (approximately 5
ml (1/8OZ) of water per 100 AH of battery capacity per cycle
assuming a 10% overcharge).
|
Absorption Time 4000 series |
2 hours |
|
Absorption Time 5000 series
(CS, KS plate types) |
3 hours
|
|
Equalization Time - Preventive |
2-3 hours |
Equalization - Corrective
Corrective equalization needs to be
performed if symptoms arise such as a constantly running
generator (low capacity) or the battery bank will “not hold
a charge”. These symptoms are typical of a heavily sulfated
battery. If a battery is not being fully charged on a
regular basis or limited equalization is performed using a
generator (see Bulletin 611, Generators, Inverters and
Equalization) sulfation will occur from “deficit” cycling.
This undercharge condition can take months before it becomes
a major and noticeable problem. This under charge condition
is caused when batteries are deficit cycled. The bank
receives less of a charge each cycle and starts to sulfate.
Eventually the sulfate will cause a resistance to charge and
a “false high voltage” reading will occur. The “false high
voltage” is measured by the charge controller, which further
lowers the charging current to maintain the voltage set
point. This further increases the undercharge condition.
This is one reason why specific gravity measurements are so
important as “false high voltage” readings can be
misleading. See Bulletin 609, Voltage, SG and State of
Charge for information on how to correctly interpret voltage
readings.
Amperage hour meters can compound the problem and cause
people to believe they are returning the correct amount of
energy back into the batteries to maintain a good state of
charge. Amp-hr meters should be thought of as simply a fuel
gauge that does not measure state of charge directly but
indirectly. The state of charge is determined by using an
equation (peukert's equation). Sometimes there can be
fundamental errors with factors used in these calculations.
You should always confirm, at least initially, state of
charge by taking a specific gravity measurement of one cell
when it is thought the bank is fully charged.
Corrective Equalization
- Method
Corrective Equalization can take a
very long time depending on the degree of sulfation. It is
not recommended to equalize with a generator as some
generators produce low grade AC that is not properly
filtered by the inverter. This is especially true at higher
voltages.
1. If you have hydrocaps remove during equalization.
2. Set charging controls to the highest voltage allowable by
the charge controller (inverter). If the bank is severely
sulfated or available current is very limited, charge
control can be removed or by-passed. Temperature should be
monitored very, very closely and keep below 125ºF.
3. Charge at a low DC current (5 A per 100 AH of battery
capacity). If grid power is not available use solar panels
or a good DC source when possible. At high voltages,
charging with generator can be difficult and hard on the
inverter.
4. Once an hour, measure and record the specific gravity and
temperature of a test cell. If the temperature rises above
115ºF (46ºC) and approaches 125ºF (52ºC) remove the
batteries from charge. (For temperature measurement choose a
center cell, if applicable).
5. If severely sulfated, it may take many hours for the
specific gravity to rise.
6. Once the specific gravity begins to rise the bank voltage
will most likely drop or the charging current will increase.
The charging current may need to be lowered if temperature
approaches 125ºF (46ºC). If the charge controller was by
passed, it should now be used or put back in line.
7. Continue measuring the specific gravity until 1.265 is
reached.
8. Charge for another 3 hours. Add water to maintain the
electrolyte above the plates.
9. Allow bank to cool and check and record the specific
gravity of each cell. The gravities should be 1.265 ± 0.005
or lower. Check the cell electrolyte levels and add water IF
necessary.
To avoid this situation it is recommended that a specific
gravity reading of one pilot cell is measured and recorded
on a regular basis when it is thought that the bank is fully
charged. The measurement should be compared to previous
readings. If the measurement is lower than the previous
reading a longer absorption time and higher voltage setting
should be used. Note as stated above, the longer the
absorption time and the higher the bulk voltage, the more
water will be consumed but less equalization will be
required. Note: the specific gravity should rise as the
cells use water. Look for trends in the specific gravity
over a period of time and make very small adjustments as
necessary.
Caution:
If you have HYDROCAPS, remove during
equalization.
Pulse Charging
Pulse charging, has shown, that
banks do not get as severely sulfated as ones with
traditional 3 step charging when subjected to the same
undercharge conditions. Pulse charging will lower the degree
of sulfation but it will not eliminate the need for a
controlled, preventive equalization. The benefit of pulse
charging, is the bank will need less overcharge and hence
less maintenance.
Battery Additives
Most battery additives are mainly a
form of a common preservative, EDTA. These additives help to
increase the solubility of the sulfate in the electrolyte
(common salt effect). Some additives contain cadmium sulfate
and this could cause disposal problems in the future. These
additives are not beneficial and are not recommended. |