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The most accurate and direct way to test the state of
charge of a battery cell is to determine the specific
gravity of the battery electrolyte. The higher the specific
gravity of the electrolyte the higher the state of charge.
The best way to truly monitor your system over it lifetime
is to regularly take and record specific gravity readings.
Unfortunately hydrometers are not easy to use. Testing
can be time consuming, there are possibilities for error and
safety must be considered. For these reasons we present this
bulletin.
Hydrometer Types
Hydrometers come in many sizes and shapes. We recommend a
hydrometer with a float, contained in a glass vessel with a
rubber bulb to draw the acid into the tube. Stay away from
floating colored balls as the extra inaccuracy results in
very subjective testing. The hydrometer should give you a
numeric reading directly from the instrument. A good
hydrometer is accurate to +/- 0.005 points so 1.265 could
read from 1.260-1.270. The instrument accuracy should be
known.
Checking Calibration
As with all measuring equipment drawing conclusions from
the results is not worth the effort if the equipment is not
calibrated.
The correct way to check the calibration of a hydrometer
is to test the hydrometer against a known master that is
accurate to one more decimal point. These hydrometers are;
however, very expensive ($100-150 USD) and can be easily
broken.
The simplest and cheapest way, when facilities exist, is
to measure out a volume of acid and weigh it. A small
graduated cylinder and an electronic balance are perfect.
The specific gravity is then calculated as follows:
SG = Mass (g) / Volume (ml)
The metric units must be used to convert to the specific
gravity scale based on water. The hydrometer is calibrated
if it agrees with the sample within its manufacturing
tolerance.
Method of Use
Exact procedures is instrument dependent and this is
given as a general procedure and assumes a hydrometer with
glass float and body.
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Put on eye protection and rubber gloves. See bulletin
607, Basic Lead Acid Battery Safety Principals
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It is recommended to disconnect the battery especially
if on a high rate of charge / discharge.
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Remove vent cap. Carefully insert the hydrometer into
cell, not pushing down on the top of the plates.
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Carefully draw liquid into the hydrometer and avoid
"bumping" the hydrometer. Be careful the float is not
flooded (too much liquid) or sticking to the sides of the
glass tube.
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Obtain a reading by looking directly at the float.
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Repeat steps 3-5 to reconfirm reading.
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RECORD the cell number and result.
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If it is very warm or very cold correct the specific
gravity for temperature. If the ambient temperature is
fairly consistent and original gravities are taken when
the batteries are put into service temperature correction
is not as critical and only necessary if problems arise.
Make sure electrolyte is not hot if just taken out of
service. Let it reach room temperature.
An easy procedure is to number the cells starting with
the positive cell and move from cell to cell towards the
negative terminal. If this is part of a preventive
maintenance program it is helpful to number the batteries.
Temperature Correction
SG of acid is temperature dependent. If the temperature
is very cold or very hot this can lead to incorrect
readings. To correct for temperature use the following
equations the equations or below 70ºF subtract points (0.03
per 10ºF) and above 70ºF add points.
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Correction factor = (0.331 x T/ºF - 23) / 100 or 0.03
pts per 10 ºF
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Correction factor = (0.595 x T/ºF - 12.5) / 100 or 0.03
pts per 5 ºC
This is valid for 0-130ºF or -17.8- 54.4ºC
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